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AIST
研　究　紹　介

分子テンプレート

特徴
  • 固体表面の高度化・高機能化に向けて、任意の機能性分子を表面に配列・固定化させるための基盤技術。
  • アルキル修飾した平板上分子を平滑面上に物理吸着させ、修飾したアルキル鎖長により 分子の配列や間隔を制御。
コンセプト
Concept of molecular template
分子テンプレートの例
STM image of molecular template

関連文献

  1. "Rotational Libration of a Double-Decker Porphyrin Visualized"
    J. Otsuki, Y. Komatsu, D. Kobayashi, M. Asakawa, and K. Miyake
    Journal of the American Chemical Society 132(20), 6870-6871 (2010).

  2. "Molecular Motion of Surface-Immobilized Double-Decker Phthalocyanine Complexes"
    K. Miyake , M. Fukuta, M. Asakawa, Y. Hori, T. Ikeda and T. Shimizu
    Journal of the American Chemical Society, 131(49), 17808-17813 (2009).

  3. "Scanning Tunneling Microscopy Observation of Self-Assembled Monolayers of Strapped Porphyrins"
    T. Ikeda, M. Asakawa, K. Miyake , M. Goto, and T. Shimizu
    Langmuir 24(22), 12877-12882 (2008).

  4. "Alkyl Chain Length Dependence of the Self-organized Structure of Alkyl-substituted Phthalocyanines"
    K. Miyake , Y. Hori, T. Ikeda, M. Asakawa, T. Shimizu, and S. Sasaki
    Langmuir 24(9), 4708-4714 (2008).

  5. "Nanoscale to Macroscale Investigation of the Frictional Properties of Physisorbed Layers of Self-Organized Phthalocyanine Derivatives"
    K. Miyake , M. Nakano, A. Korenaga, Y. Hori, T. Ikeda, M. Asakawa, T. Shimizu, S. Sasaki, and Y. Ando
    Tribology Letters 31(1), 9-15 (2008).

  6. "STM Observation of Labile Axial Ligands to Zinc-Porphyrin at Liquid/Solid Interface"
    J. Otsuki, E. Seki, T. Taguchi, M. Asakawa, and K. Miyake
    Chemistry Letters 36(6), 740-741 (2007).

  7. "Self-assembly of bipyridine derivatives at solid/liquid interface: effects of the number of peripheral alkyl chains and metal coordination on the two-dimensional structures"
    Y. Kikkawa, E. Koyama, S. Tsuzuki, K. Fujiwara, K. Miyake , H. Tokuhisa, and M. Kanesatoa
    Surface Science 601, 2520-2524 (2007).

  8. "Odd-even Effect and Metal Induced Structural Convergence in Self-Assembled Monolayers of Bipyridine Derivatives"
    Y. Kikkawa, E. Koyama, S. Tsuzuki, K. Fujiwara, K. Miyake , H. Tokuhisa, and M. Kanesatoa
    Chemical Communication, 1343-1345 (2007).

  9. "Two-Dimensional Structure Control by Molecular Width Variation with Metal Coordination"
    Y. Kikkawa, E. Koyama, S. Tsuzuki, K. Fujiwara, K. Miyake , H. Tokuhisa, and M. Kanesatoa
    Langmuir 22(16), 6910-6914 (2006).

  10. "Arrays of Double-Decker Porphyrins on Highly Oriented Pyrolytic Graphite"
    J. Otsuki, S. Kawaguchi, T. Yamakawa, M. Asakawa, and K. Miyake
    Langmuir 22(13), 5708-5715 (2006).

  11. "Surface Patterning with Two-Dimensional Porphyrin Supramolecular Arrays"
    J. Otsuki, E. Nagamine, T. Kondo, K. Iwasaki, M. Asakawa, and K. Miyake
    Journal of the American Chemical Society 127(29), 10400-10405 (2005).

  12. "Alkyl-Chain Length Dependence of Frictional Properties of Alkyl-Substituted Phthalocyanines Physisorbed on Graphite Surface"
    K. Miyake , Y. Hori, T. Ikeda, M. Asakawa, T. Shimizu, T. Ishida, and S. Sasaki
    Japanese Journal of Applied Physics 44(7B), 5403-5408 (2005).

  13. "Synthesis of Alkyl-substituted, Strapped Porphyrin to Prepare Stable Alkyl-chain-assisted Self-assembled Monolayers of Porphyrin Conjugates"
    T. Ikeda, M. Asakawa, K. Miyake , and T. Shimizu
    Chemistry Letters 33(11) 1418-1419 (2004).

  14. "STM Observation of Alkyl Chain-Assisted Self-Assembled Monolayers of Pyridine-Coordinated Porphyrin Rhodium Chlorides"
    T. Ikeda, M. Asakawa, M. Goto, K. Miyake , T. Ishida, and T. Shimizu
    Langmuir 20(13), 5454-5459 (2004).