学術論文

Accepted Manuscript

55.　"Amination-Degradation of Super Engineering Plastics for the Construction of Surface Emissive Resin Materials"
　Yasunori Minami, Shunsuke Tsuyuki, Ryota Watanabe, Nobuyasu Itoh, Masaru Yoshida
　 Commun. Chem. in press.


2026 - 2019

54.　"Degradation of Anhydride-cured Epoxy Thermosetting Resins Promoted by Two-phase Water ionic Liquid Mixtures"
　Yasunori Minami, Takako Kato, Douglas Hungwe, Yuki Yamasaki, Kazuhiko Sato, Masaru Yoshida
　 ChemSusChem 2026, 19, e202502692.


53.　"1,6-Disila[4.4.4]propellane Revisited ? Part 1: Improved Synthesis by a Mechanistically Logical Fluorosilane Route and Its Structural Aspects Including Linear Stacking along the Si-Si Bond in the Crystalline State"
　 Suguru Kobayashi, Takahiro Sasamori, Yumiko Nakajima, Yasunori Minami, Kosuke Iizuka, Tomoyuki Saeki, Akio Toshimitsu, Hayato Tsuji, Shigehiro Yamaguchi, Aiko Fukazawa, Tomokatsu Kushida, Daisuke Hashizume, Kohei Tamao
　 Bull. Chem. Soc. Jpn. 2026, 99, uoaf119.

52.　"Facile Depolymerization of Thermally Stable Polyetherethersulfone and Polyetheretherketone Using Hydroquinone and Bases"
　 Yasunori Minami,* Rena Honobe, Shunsuke Tsuyuki, Kazuhiko Sato, Masaru Yoshida
　 ChemSusChem 2025, 18, e202401778.
　(Selected as Very Important Paper)


51.　"Degradation of stable thermosetting epoxy resins mediated by bases in amide solvents"
　Yasunori Minami, Tomoo Tsuyuki, Hayato Ishikawa, Yoshihiro Shimoyama, Kazuhiko Sato, Masaru Yoshida
　 Polymer J. 2025, 57, 149-162.
　プレスリリース： 産総研，JST.


50.　"Alcoholysis of oxyphenylene-based super engineering plastics mediated by readily available bases"
　 Yasunori Minami, Rena Honobe, Yuuki Inagaki, Kazuhiko Sato, Masaru Yoshida
　 Polymer J. 2024, 56, 369-377.

49.　"Catalytic thiolation-depolymerization-like decomposition of oxyphenylene-type super engineering plastics via selective carbon-oxygen main chain cleavages"
　 Yasunori Minami, Sae Imamura, Nao Matsuyama, Yumiko Nakajima, Masaru Yoshida
　 Commun. Chem. 2024, 7, 37.


48.　"Hydroxylation-depolymerization of oxyphenylene-based super engineering plastics to regenerate arenols"
　Yasunori Minami, Yuuki Inagaki, Tomoo Tsuyuki, Kazuhiko Sato, Yumiko Nakajima
　 JACS Au 2023, 3, 2323-2332.
　プレスリリース： 産総研，JST.
　(selected as JACS Au ECAB Selects)


47.　"Depolymerization of robust polyetheretherketone to regenerate monomer units using sulfur reagents"
　 Yasunori Minami, Nao Matsuyama, Yasuo Takeichi, Ryota Watanabe, Siby Mathew, and Yumiko Nakajima
　 Commun. Chem. 2023, 6, 14.
　プレスリリース： 産総研，JST.
　 2023 Editors’ Highlights in Commun. Chem.


46.　"Synthesis of Multisubstituted Benzenes from Phenols via Multisubstituted Benzynes"
　Akira Nagai, Akihiro Kobayashi, Yuki Sakata, Yasunori Minami, Keisuke Uchida, Takamitsu Hosoya, Suguru Yoshida
　Synthesis 2022, 54, 5017-5025.

45.　"Radical Hydrodehalogenation of Aryl Halides with H2 Catalyzed by a Phenanthroline-Based PNNP Cobalt(I) Complex"
　Nai-Yuan Jheng, Yusuke Ishizaka, Yuki Naganawa, Yasunori Minami, Akira Sekiguchi, Kosuke Iizuka, Yumiko Nakajima
　ACS Catal. 2022, 12, 2320-2329.

44.　"Catalytic Reductive Cleavage of Poly(phenylene sulfide) using a Hydrosilane"
　Yasunori Minami, Nao Matsuyama, Yasuaki Matsuo, Masanori Tamura, Kazuhiko Sato, Yumiko Nakajima
　 Synthesis 2021, 53, 3351-3354.

43.　"Palladium/carboxylic acid-catalyzed Alkenylation of Furfural and its Derivatives Using Alkynes"
　 Yasunori Minami, Hitomi Miyamoto, Yumiko Nakajima
　 ChemCatChem 2021, 13, 855-858.

42.　"Allyl Monitorization of the Regioselective Pd-Catalyzed Annulation of Alkylnyl Aryl Ethers leading to Bismethylenechromanes"
　Marti Gimferrer, Massimo Christian D’Alterio, Giovanni Talarico, Yasunori Minami, Tamejiro Hiyama, Albert Poater
　 J. Org. Chem. 2020, 85, 12262-12269.

41.　"Synthesis of Multisubstituted Cycloalkenes through Carbomagnesiation of Transient Cycloalkynes"
　 Yuya Tamura, Yasunori Minami, Yoshitake Nishiyama, Yuki Sakata, Fumika Karaki, Takamitsu Hosoya, Suguru Yoshida
　 Chem. Commun. 2020, 56, 7147-7150.

40.　"Facile Construction of Furanoacenes by a Three-step Sequence Going Through Disilyl-exo-cyclic Dienes"
　 Yasunori Minami, Yuki Furuya, Tamejiro Hiyama
　 Chem. Eur. J. 2020, 26, 9471-9474.

39.　"Synthesis of Diverse γ-Aryl-?-ketoesters via Aryne Intermediates Generated by C-C Bond Cleavage"
　Keisuke Uchida, Yasunori Minami, Suguru Yoshida, Takamitsu Hosoya
　Org. Lett. 2019, 21, 9019-9023.

38.　"Synthesis of Phosphaphenalenium Salts via P?C Reductive Elimination at a Ru(II) Center and Their Fluorescence Properties"
　Takahiro Kato, Takuya Kuwabara, Yasunomi Minami, Tamejiro Hiyama, Youichi Ishii
　Bull. Chem. Soc. Jpn. 2019, 92, 1131-1141.

37.　"Cross-coupling Reaction of Aryl(triethyl)silanes with Aryl Chlorides: An Easy Access to Oligothiophenes"
　Takeshi Komiyama, Yasunori Minami, Tamejiro Hiyama
　 Chem. Lett. 2019, 48, 361-363.

2018-
36.　"Synthesis of 1-Substituted 1,3-Dioxybuta-1,3-dienes by Palladium-catalyzed Addition of Methyl Ketones to an Aryl Silylethynyl Ether"
　Yasunori Minami, Yuta Noguchi, Mayu Yamada, Chisato Tsuruoka, Yuki Furuya, Tamejiro Hiyama
　 Chem. Lett. 2018, 47, 1288-1291. (Open Access)
　Selected as Editor's Choice

35.　"Synthesis of Indenes by Intramolecular anti-Hydroarylation of Propargylarenes"
　Yasunori Minami, Takumi Sakamaki, Yuki Furuya, Tamejiro Hiyama
　 Chem. Lett. 2018, 47, 1151-1153.

34.　"Copper-catalyzed Cross-coupling Reaction between Aryl(trialkyl)silanes and Alkyl Halides"
　Takeshi Komiyama, Yasunori Minami, Tamejiro Hiyama
　 Chem. Lett. 2018, 47, 1048-1050.

33.　"Palladium/Acid-Catalyzed Straightforward Allylation of Arenes using 1-Substituted Propynes via Aryl C-H Bond Activation"
　Yasunori Minami, Yuki Furuya, Tamejiro Hiyama
　 Asian J. Org. Chem. 2018, 7, 1343-1346. (Open Access)

32.　"P-C Reductive Elimination in Ru(II) Complexes to Convert Triarylphosphine Ligands into Five- or Six-membered Phosphacycles Fused with Aromatic Systems"
　Takuya Kuwabara, Takahiro Kato, Kouichi Takano, Shintaro Kodama, Yuuka Manabe, Noriko Tsuchida, Keiko Takano, Yasunori Minami, Tamejiro Hiyama, Youichi Ishii
　 Chem. Commun. 2018, 54, 5357-5360.

31.　"Monitor the Phosphine Role in the Mechanism of the Palladi-um catalyzed Benzosiloles Formation from Aryloxyethynyl Silanes"
　Marti Gimferrer, Yasunori Minami, Yuta Noguchi, Tamejiro Hiyama, Albert Poater
　 Organometallics 2018, 37, 1456-1461.

30.　"Alkenylation of Arenes using Disubstituted Ethynes by Palladium/Carboxylic Acid Catalysis"
　Yasunori Minami, Yuki Furuya, Tatsuro Kodama, Tamejiro Hiyama
　 Chem. Lett. 2018, 47, 674. (Open Access)

29.　"Synthesis of Ferrocene-Fused Pyrans through Alkynoxy-Directed C-H Activation/Cyclization"
　Takashi Mitsui, Yuichiro Tokoro, Ryosuke Haraguchi, Kengo Sugita, Masato Harada, Shin-ichi Fukuzawa, Yasunori Minami, Tamejiro Hiyama
　 Bull. Chem. Soc. Jpn. 2018, 91, 839-845.

28.　"Palladium/Copper Dual Catalysis for Cross-coupling of Aryl(trialkyl)silanes with Aryl Bromides"
　Takeshi Komiyama, Yasunori Minami, Yuki Furuya, Tamejiro Hiyama
　 Angew. Chem. Int. Ed. 2018, 57, 1987-1990.
　Selected as "Hot Paper".　　 　Highlighted in Synfacts 2018, 14, 296.

27.　"Activation of a Carbon-Carbon Bond in Internal Alkynes: Vinylidene Rearrangement of Disubstituted Alkynes at an Ir Complex"
　Takuya Kuwabara, Shuhei Takamori, Satoshi Kishi, Takahiro Watanabe, Yousuke Ikeda, Shintaro Kodama, Yasunori Minami, Tamejiro Hiyama, Youichi Ishii
　 Synlett 2018, 29, 727-730.
　Published as part of the Cluster C-C Activation

26.　"Synthesis of Benzosiloles by Intramolecular anti-Hydroarylation via ortho-C?H Activation of Aryloxyethynyl silanes"
　Yasunori Minami, Yuta Noguchi, Tamejiro Hiyama
　 J. Am. Chem. Soc. 2017, 139, 14013-14016.

25.　"Hydroarylation of 2-Aryloxybut-1-en-3-ynes via Pd/acid-catalyzed C-H bond activation: Concise Synthesis of 2,3-Bismethylene-2,3-dihydrobenzofurans"
　Yasunori Minami, Megumi Sakai, Takumi Sakamaki, Tamejiro Hiyama
　 Chem. Asian J. 2017, 12, 2399-2403.

24.　"Nickel-catalyzed N-Arylation using N-TMS-carbazole"
　Yasunori Minami, Takeshi Komiyama, Kenta Shimizu, Shu-ichi Uno, Tamejiro Hiyama, Osamu Goto, Hideyuki Ikehira
　 Synlett 2017, 28, 2407-2410.
　Published as part of the Cluster Silicon in Synthesis and Catalysis
　Highlighted in Synfacts 2017, 13, 1029.

23.　"Facile One-pot Synthesis of Solid-state Luminescent Benzopyrylium Tetrafluoroborates Derived from Annulation of Aryl Silylethynyl Ethers with Alkynes"
　Yasunori Minami, Yuichiro Tokoro, Mayu Yamada, Tamejiro Hiyama
　 Chem. Lett. 2017, 46, 899-902.

22.　"Aryl(triethyl)silanes for Biaryl and Teraryl Synthesis by Copper(II)-Catalyzed Cross-coupling Reaction"
　Takeshi Komiyama, Yasunori Minami, Tamejiro Hiyama
　 Angew. Chem. Int. Ed. 2016, 55, 15787-15791.
　Corrigendum: Angew. Chem. Int. Ed. 2017, 56, 8035.
　Highlighted in Synfacts 2017, 13, 151.

21.　"Intramolecular Hydroalkylation via Activation of tert-Butyl C-H Bond in Silylethynyl Aryl Ethers"
　Yasunori Minami, Yuta Noguchi, Kotomi Yamada, Tamejiro Hiyama
　 Chem. Lett. 2016, 45, 1210. (Open Access)
　Selected as Editor's Choice

20.　"Annulation of Alkynyl Aryl Ethers with Allyl Pivalates to give 2,3-Bismethylenechromanes through Double C-H Bond Cleavage"
　Yasunori Minami, Megumi Sakai, Tomohiro Anami, Tamejiro Hiyama
　 Angew. Chem. Int. Ed. 2016, 55, 8701.

19.　"Dehydrogenative Carbon-Carbon Bond Formation Reactions Using Alkynoxy Moieties as Hydrogen-accepting Directing Groups"
　Yasunori Minami, Tatsuro Kodama, Tamejiro Hiyama
　 Angew. Chem. Int. Ed. 2015, 54, 11813.

18.　"Alkynoxy-directed C-H Functionalizations: Palladium(0)-catalyzed Annulations of Alkynyl Aryl Ethers with Alkynes"
　Yasunori Minami, Yuki Shiraishi, Tatsuro Kodama, Mayuko Kanda, Kotomi Yamada, Tomohiro Anami, Tamejiro Hiyama
　 Bull. Chem. Soc. Jpn. 2015, 88, 1388.　 　"Selected Paper"

17.　"Catalytic Carbon-Nitrogen Bond-forming Cross-coupling using N-Trimethylsilylamines"
　Yasunori Minami, Takeshi Komiyama, Kenta Shimizu, Tamejiro Hiyama, Osamu Goto, Hideyuki Ikehira
　 Bull. Chem. Soc. Jpn. 2015, 88, 1437.

16.　"Straightforward Synthesis of HOMSi Reagents via sp2C-H Silylation"
　Yasunori Minami, Takeshi Komiyama, Tamejiro Hiyama
　 Chem. Lett. 2015, 44, 1065. (Open Access)
　Selected as Editor's Choice

15.　"Palladium-Catalyzed Annulation of Alkynyl Aryl Ethers with Isocyanates through o-C-H Cleavage. 　Synthesis of Solid-state Emissive 2-Methylidene-2H-1,4-benzoxazin-3(4H)-ones"
　Yasunori Minami, Mayuko Kanda, Megumi Sakai, Tamejiro Hiyama
　 Tetrahedron 2015, 71, 4522.

14.　"Palladium-catalyzed Annulation of 2-Substituted Silylethynyloxyarenes through δ-C-H Activation"
　Minami Yasunori; Anami Tomohiro; Hiyama Tamejiro
　 Chem. Lett. 2014, 43, 1791. (Open Access)
Selected as Editor's Choice

13.　"Palladium-catalyzed Cycloaddition of Silylethynyl Aryl Ethers with Isocyanates via o-C-H cleavage"
　Minami Yasunori; Kanda Mayuko; Hiyama Tamejiro
　 Chem. Lett. 2014, 43, 1408. (Open Access)

12.　"Silicon-Based C-N Cross-Coupling Reaction"
　Shimizu Kenta; Minami Yasunori; Goto Osamu; Ikehira Hideyuki; Hiyama Tamejiro
　 Chem. Lett. 2014, 43, 438.

11.　"Synthesis of HOMSi Reagents by Pd/Cu-Catalyzed Silylation of Bromoarenes with Disilanes"
　Minami Yasunori; Shimizu Kenta; Tsuruoka Chisato; Komiyama Takeshi; Hiyama Tamejiro
　 Chem. Lett. 2014, 43, 201.

10.　"Palladium-catalyzed Cycloaddition of Alkynyl Aryl Ethers to Allenes to Form a 2,3-Bismethylidene-2,3-dihydro-4H-1-benzopyran Framework"
　Minami Yasunori; Kanda Mayuko; Hiyama Tamejiro
　 Chem. Lett. 2014, 43, 181. (Open Access)

9.　"Palladium-Catalyzed Hydrobenzylation of ortho-Tolyl Alkynyl Ethers by Benzylic C-H Activation: Remarkable Alkynoxy-Directing Effect"
　Minami Yasunori; Yamada Kotomi; Hiyama Tamejiro
　 Angew. Chem. Int. Ed. 2013, 52, 10611.

8.　"Highly Chemoselective Carbon-Carbon σ-Bond Activation: Nickel/Lewis Acid-Catalyzed Polyfluoroarylcyanation of Alkynes"
　Minami Yasunori; Yoshiyasu Hirofumi; Nakao Yoshiaki; Hiyama Tamejiro
　 Angew. Chem. Int. Ed. 2013, 52, 883.
　Highlighted in Synfacts 2013, 729.

7.　"Polyarylene Synthesis by Cross-Coupling with HOMSi Reagents"
　Shimizu Kenta; Minami Yasunori; Nakao Yoshiaki; Ohya Ken-ichiro; Ikehira Hideyuki; Hiyama Tamejiro
　 Chem. Lett. 2013, 42, 45.

6.　"Palladium-catalyzed cycloaddition of alkynyl aryl ethers with internal alkynes via selective ortho-C-H activation"
　Minami Yasunori; Shiraishi Yuki; Yamada Kotomi; Hiyama Tamejiro
　 J. Am. Chem. Soc. 2012, 134, 6124. selected as "Top 20 most read article"

5.　"Pd-Catalyzed Regioselective Iminothiolation of Alkynes: A Remarkable Effect of the CF3 Group of Iminosulfides"
　Minami Yasunori; Kuniyasu Hitoshi; Sanagawa Atsushi; Kambe Nobuaki
　Org. Lett. 2010, 12, 3744-3747.

4.　"Transition-Metal-Catalyzed Regioselective Aroyl- and Trifluoroacetylthiolation of Alkynes Using Thioesters."
　Minami, Yasunori; Kuniyasu, Hitoshi; Miyafuji, Kiyoshi; Kambe, Nobuaki
　Chem. Commun. 2009, 3080-3082.

3.　"One-Pot Syntheses of 2,3-Dihydrothiopyran-4-one Derivatives by Pd/Cu-Catalyzed Reactions of α,β-Unsaturated Thioesters with Propargyl Alcohols"
　Minami, Yasunori; Kuniyasu, Hitoshi; Kambe, Nobuaki
　Org. Lett. 2008, 10, 2469-2472.

2.　"Reactions of α,β-Unsaturated Thioesters with Pt(0): Implication of Dual Mechanism Leading to the Formation of Acyl Platinum"
　Minami, Yasunori; Kato, Tomohiro; Kuniyasu, Hitoshi; Terao, Jun; Kambe, Nobuaki
　Organometallics 2006, 25, 2949-2959.

1.　""β-cis-SAr effect" on decarbonylation from α,β-unsaturated acyl and aroyl complexes. "
　 Kato, Tomohiro; Kuniyasu, Hitoshi; Kajiura, Takamichi; Minami, Yasunori; Ohtaka, Atsushi; Kinomoto, Masanori; Terao, Jun; Kurosawa, Hideo; Kambe, Nobuaki
　Chem. Commun. 2006, 868-869.