産総研

Higashino's Homepage

Last updated 2020.10.22
写真
東野 寿樹(Toshiki Higashino)
国立研究開発法人 産業技術総合研究所
電子光基礎技術研究部門
メゾスコピック材料グループ 研究員
〒305-8565 茨城県つくば市東1-1-1 つくば中央第5-41
TEL:029-861-5929
E-mail:t-higashino_at_aist.go.jp (_at_を@に)
略歴
  • 2015年3月 東京工業大学大学院 理工学研究科 有機・高分子物質専攻 博士課程修了(工学博士)
  • 2015年4月〜2017年3月 東京大学 物性研究所 新物質科学研究部門 特任研究員
  • 2017年4月〜2019年3月 産業技術総合研究所 フレキシブルエレクトロニクス研究センター 研究員
  • 2019年4月〜 現職

専門分野
  • 有機合成化学,構造有機化学,有機材料化学

所属学協会
  • 日本化学会,分子科学会,応用物理学会

論文

  1. S. Inoue. T. Higashino, S. Arai, R. Kumai, H. Matsui, S. Tsuzuki, S. Horiuchi, T. Hasegawa, "Regioisomeric Control of Layered Crystallinity in Solution-Processable Organic Semiconductors", Chem. Sci., in press. (DOI: 10.1039/D0SC04461J)


  2. G. Kitahara, S. Inoue, T. Higashino, M. Ikawa, T. Hayashi, S. Matsuoka, S. Arai, T. Hasegawa, "Meniscus-controlled printing of single-crystal interfaces showing extremely sharp-switching transistor operation", Sci. Adv. 2020, 6, eabc8847. (DOI: 10.1126/sciadv.abc8847)


  3. T. Higashino, K. Kuribara, N. Toda, S. Uemura, H. Tachibana, R. Azumi, "Direct Preparation of Mixed Self-Assembled Monolayers Based on Common-Substructure-Tailored Phosphonic Acids for Fine Control of Surface Wettability", Chem. Lett. 2020, 49, 1302−1305. (DOI: 10.1246/cl.200460)
  4. Graphical Abstract

  5. T. Kadoya, S. Sugiura, K. Tahara, T. Higashino, K. Kubo, T. Sasaki, K. Takimiya, J. Yamada, "Two-dimensional radical-cationic Mott insulator based on an electron donor containing neither tetrathiafulvalene nor tetrathiapentalene skeleton", CrystEngComm 2020, 22, 5949−5953. (DOI: 10.1039/D0CE00878H)
  6. Graphical Abstract

  7. T. Higashino, S. Arai, S. Inoue, S. Tsuzuki, Y. Shimoi, S. Horiuchi, T. Hasegawa, R. Azumi, "Architecting layered molecular packing in substituted benzobisbenzothiophene (BBBT) semiconductor crystals", CrystEngComm 2020, 22, 3618−3626. (DOI: 10.1039/D0CE00285B)
  8. Graphical Abstract

  9. K. Tahara, Y. Ashihara, T. Higashino, Y. Ozawa, T. Kadoya, K. Sugimoto, A. Ueda, H. Mori, M. Abe, "New π-extended catecholato complexes of Pt(II) and Pd(II) containing a benzothienobenzothiophene (BTBT) moiety: synthesis, electrochemical behavior and charge transfer properties", Dalt. Trans. 2019, 48, 7367−7377. (DOI: 10.1039/C8DT05057K)
  10. Graphical Abstract

  11. S. Yokomori, A. Ueda, T. Higashino, R. Kumai, Y. Murakami, H. Mori, "Construction of three-dimensional anionic molecular frameworks based on hydrogen- bonded metal dithiolene complexes and the crystal solvent effect", CrystEngComm 2019, 21, 2940−2948. (DOI: 10.1039/C9CE00364A)
  12. Graphical Abstract

  13. T. Higashino, S. Inoue, Y. Sadamitsu, S. Arai, S. Horiuchi, T. Hasegawa, "Bilayer-type layered herringbone packing in 3-n-octyl-9-phenyl-benzothieno[3,2-b]naphtho[2,3-b]thiophene", Chem. Lett. 2019, 48, 453−456. (DOI: 10.1246/cl.181038)
  14. Graphical Abstract

  15. R. Sato, D. Yoo, T. Higashino, T. Mori, "n-Channel Transistor of 1,5-Dibromo-2,6-naphthoquinhydrone", Chem. Lett. 2019, 48, 264−266. (DOI: 10.1246/cl.181002)
  16. Graphical Abstract

  17. T. Kadoya, R. Oki, Y. Kiyota, Y. Koyama, T. Higashino, K. Kubo, T. Mori, J. Yamada, "Transport Properties of Molecular Conductors (BSBS)2XF6 (X = As, Sb, and Ta): Investigation of Intermolecular Transfer Integrals in the Radical-Cationic State of Benzothienobenzothiophene-Type Semiconductors", J. Phys. Chem. C 2019, 123, 5216−5221. (DOI: 10.1021/acs.jpcc.8b10687)
  18. Graphical Abstract

  19. T. Higashino, A. Ueda, H. Mori, "Di- and Tetramethoxy Benzothienobenzothiophenes: Substitution Position Effects on the Intermolecular Interactions, Crystal Packing and Transistor Properties", New J. Chem. 2019, 43, 884−892. (DOI: 10.1039/C8NJ04251A)
  20. Graphical Abstract

  21. T. Higashino, A. Ueda, J. Yoshida, H. Mori, "Improved Stability of a Metallic State in Benzothienobenzothiophene-Based Molecular Conductors: An Effective Increase of Dimensionality with Hydrogen Bonds", Chem. Commun. 2017, 53, 3426−3429. (DOI: 10.1039/c7cc00784a) Inside Back Cover
  22. Graphical Abstract

  23. K. Iijima, Y. Le Gal, T. Higashino, D. Lorcy, T. Mori, "Birhodanines and Their Sulfur Analogues for Air-Stable n-Channel Organic Transistors", J. Mater. Chem. C 2017, 5, 9121−9127. (DOI: 10.1039/c7tc02886e)
  24. Graphical Abstract

  25. R. Sato, M, Dogishi, T. Higashino, T. Kadoya, T. Kawamoto, T. Mori, "Charge-Transfer Complexes of Benzothienobenzothiophene with Tetracyanoquinodimethane and the n-Channel Organic Field-Effect Transistors", J. Phys. Chem. C 2017, 121, 6561−6568. (DOI: 10.1021/acs.jpcc.7b00902)
  26. Graphical Abstract

  27. T. Higashino, M. Dogishi, T. Kadoya, R. Sato, T. Kawamoto, T. Mori, "Air-Stable n-Channel Organic Field-Effect Transistors Based on Charge-Transfer Complexes Including Dimethoxybenzothienobenzothiophene and Tetracyanoquinodimethane Derivatives", J. Mater. Chem. C ,2016, 4, 5981−5987. (DOI: 10.1039/c6tc01532h)
  28. Graphical Abstract

  29. C. Fujisue, T. Kadoya, T. Higashino, R. Sato, T. Kawamoto, T. Mori, "Air-Stable Ambipolar Organic Transistors Based on Charge-Transfer Complexes Containing Dibenzopyrrolopyrrole", RSC Adv. 2016, 6, 53345−53350. (DOI: 10.1039/c6ra10606d)
  30. Graphical Abstract

  31. M. Ashizawa, N. Masuda, T. Higashino, T. Kadoya, T. Kawamoto, H. Matsumoto, T. Mori, "Ambipolar Organic Transistors Based on Isoindigo Derivatives", Org. Electron. 2016, 35, 95−100. (DOI: 10.1016/j.orgel.2016.05.013)
  32. Graphical Abstract

  33. Y. Kiyota, T. Kadoya, K. Yamamoto, K. Iijima, T. Higashino, T. Kawamoto, K. Takimiya, T. Mori, "Benzothienobenzothiophene-Based Molecular Conductors: High Conductivity, Large Thermoelectric Power Factor, and One-Dimensional Instability", J. Am. Chem. Soc. 2016, 138, 3920−3925. (DOI: 10.1021/jacs.6b01213)
  34. Graphical Abstract

  35. T. Higashino, O. Jeannin, T. Kawamoto, D. Lorcy, T. Mori, M. Fourmigué, "A Single-Component Conductor Based on a Radical Gold Dithiolene Complex with Alkyl-Substituted Thiophene-2,3-dithiolate Ligand", Inorg. Chem. 2015, 54, 9908−9913. (DOI: 10.1021/acs.inorgchem.5b01678)
  36. Graphical Abstract


  37. J. Cho, T. Higashino, T. Mori, "Band-Like Transport Down to 20 K in Organic Single-Crystal Transistors Based on Dioctylbenzothienobenzothiophene", Appl. Phys. Lett. 2015, 106, 193303. (DOI: 10.1063/1.4921343)


  38. A. Filatre-Furcate, T. Higashino, D. Lorcy, T. Mori, "Air-Stable n-Channel Organic Field-Effect Transistors Based on a Sulfur Rich π-Electron Acceptor", J. Mater. Chem. C 2015, 3, 3569−3573. (DOI: 10.1039/c5tc00253b)
  39. Graphical Abstract

  40. T. Higashino, S. Kumeta, S. Tamura, Y. Ando, K. Ohmori, K. Suzuki, T. Mori, "Ambipolar Transistor Properties of 2,2′-Binaphthosemiquinones", J. Mater. Chem. C 2015, 3, 1588−1594. (DOI: 10.1039/c4tc02467b)
  41. Graphical Abstract


  42. T. Higashino, J. Cho, T. Mori, "Extracting Parameters in Ambipolar Organic Transistors Based on Dicyanomethylene Terthiophene", Appl. Phys. Express 2014, 7, 121602. (DOI: 10.7567/APEX.7.121602)


  43. O. Pitayatanakul, T. Higashino, T. Kadoya, M. Tanaka, H. Kojima, M. Ashizawa, T. Kawamoto, H. Matsumoto, K. Ishikawa, T. Mori, "High Performance Ambipolar Organic Field-Effect Transistors Based on Indigo Derivatives", J. Mater. Chem. C 2014, 2, 9311−9317. (DOI: 10.1039/c4tc01563k)
  44. Graphical Abstract

  45. T. Higashino, T. Kadoya, S. Kumeta, K. Kurata, T. Kawamoto, T. Mori, "An Organic Metal Derived from a Selenium Analogue of Benzothienobenzothiophene", Eur. J. Inorg. Chem. 2014, 3895−3898. (DOI: 10.1002/ejic.201402221)
  46. Graphical Abstract

  47. T. Kadoya, M. Ashizawa, T. Higashino, T. Kawamoto, S. Kumeta, H. Matsumoto, T. Mori, "A Highly Conducting Organic Metal Derived from An Organic-Transistor Material: Benzothienobenzothiophene", Phys. Chem. Chem. Phys. 2013, 15, 17818−17822. (DOI: 10.1039/c3cp52881b)
  48. Graphical Abstract

  49. T. Higashino, Y. Akiyama, H. Kojima, T. Kawamoto, T. Mori, "Organic Semiconductors and Conductors with tert-Butyl Substituents", Crystals 2012, 2, 1222−1238. (DOI: 10.3390/cryst2031222)
  50. Graphical Abstract