産総研

Higashino's Homepage

Last updated 2022.11.25
写真
東野 寿樹(Toshiki Higashino)
国立研究開発法人 産業技術総合研究所
電子光基礎技術研究部門
メゾスコピック材料グループ 主任研究員
〒305-8565 茨城県つくば市東1-1-1 つくば中央第5-41
TEL:029-861-5929
E-mail:t-higashino_at_aist.go.jp (_at_を@に)
略歴
  • 2015年3月 東京工業大学大学院 理工学研究科 有機・高分子物質専攻 博士課程修了(工学博士)
  • 2015年4月〜2017年3月 東京大学 物性研究所 新物質科学研究部門 特任研究員
  • 2017年4月〜2019年3月 産業技術総合研究所 フレキシブルエレクトロニクス研究センター 研究員
  • 2019年4月〜 現職

専門分野
  • 構造有機化学,有機材料化学

所属学協会
  • 日本化学会,分子科学会,応用物理学会

論文

  1. S. Yokomori, S. Dekura, A. Ueda, T. Higashino, H. Mori, "Neutral Radical Molecular Conductors Based on a Gold Dimethoxybenzenedithiolene Complex with and without Crystal Solvent", Chem. Lett., in press. (DOI: 10.1246/cl.220446)

  2. K. Nikaido, S Inoue, R. Kumai, T. Higashino, S. Matsuoka, S. Arai, T. Hasegawa, "Mixing-Induced Orientational Ordering in Liquid-Crystalline Organic Semiconductors", Adv. Mater. Interf., in press. (DOI: 10.1002/admi.202201789)

  3. S. Matsuoka, K. Ogawa, R. Ono, K. Nikaido, S. Inoue, T. Higashino, M. Tanaka, J. Tsutsumi, R. Kondo, R. Kumai, S. Tsuzuki, S. Arai, T. Hasegawa, "Highly stable and isomorphic donor-acceptor stacking in a family of n-type organic semiconductors of BTBT-TCNQ derivatives", J. Mater. Chem. C 2022, 10, 16471−16479. (DOI: 10.1039/D2TC03634G)

  4. T. Kadoya, M. Shishido, S. Sugiura, T. Higashino, K. Tahara, K. Kubo, T. Sasaki, J. Yamada, "Crystal Structures and Conducting Properties of Mott Insulator (BEDT-BDS)PF6: Selenium Substitution Effect in the Parent (BEDT-BDT)PF6", Chem. Lett. 2022, 51, 683−686. (DOI: 10.1246/cl.220148)

  5. T. Higashino, T. Mori, "Small-molecule ambipolar transistors", Phys. Chem. Chem. Phys. 2022, 24, 9770−9806. (DOI: 10.1039/D1CP05799E)

  6. S. Inoue, K. Nikaido, T. Higashino, S. Arai, M. Tanaka, R. Kumai, S. Tsuzuki, S. Horiuchi, H. Sugiyama, Y. Segawa, K. Takaba, S. Maki-Yonekura, K. Yonekura, T. Hasegawa, "Emerging Disordered Layered-Herringbone Phase in Organic Semiconductors Unveiled by Electron Crystallography", Chem. Mater. 2022, 34, 72−84. (DOI: 10.1021/acs.chemmater.1c02793)

  7. T. Higashino, S. Inoue, S. Arai, H. Matsui, N. Toda, S. Horiuchi, R. Azumi, T. Hasegawa, "Architecting Layered Crystalline Organic Semiconductors Based on Unsymmetric π-Extended Thienoacenes", Chem. Mater. 2021, 33, 7379−7385. (DOI: 10.1021/acs.chemmater.1c01972)

  8. T. Kadoya, S. Sugiura, T. Higashino, K. Tahara, K. Kubo, T. Sasaki, K. Takimiya, J. Yamada, "Dihedral-Angle Dependence of Intermolecular Transfer Integrals in BEDT-BDT-Based Radical-Cation Salts with θ-Type Molecular Arrangements", Crystals 2021, 11, 868. (DOI: 10.3390/cryst11080868)

  9. S. Inoue. T. Higashino, S. Arai, R. Kumai, H. Matsui, S. Tsuzuki, S. Horiuchi, T. Hasegawa, "Regioisomeric Control of Layered Crystallinity in Solution-Processable Organic Semiconductors", Chem. Sci. 2020, 11, 12493−12505. (DOI: 10.1039/D0SC04461J)

  10. G. Kitahara, S. Inoue, T. Higashino, M. Ikawa, T. Hayashi, S. Matsuoka, S. Arai, T. Hasegawa, "Meniscus-controlled printing of single-crystal interfaces showing extremely sharp-switching transistor operation", Sci. Adv. 2020, 6, eabc8847. (DOI: 10.1126/sciadv.abc8847)

  11. T. Higashino, K. Kuribara, N. Toda, S. Uemura, H. Tachibana, R. Azumi, "Direct Preparation of Mixed Self-Assembled Monolayers Based on Common-Substructure-Tailored Phosphonic Acids for Fine Control of Surface Wettability", Chem. Lett. 2020, 49, 1302−1305. (DOI: 10.1246/cl.200460)

  12. T. Kadoya, S. Sugiura, K. Tahara, T. Higashino, K. Kubo, T. Sasaki, K. Takimiya, J. Yamada, "Two-dimensional radical-cationic Mott insulator based on an electron donor containing neither tetrathiafulvalene nor tetrathiapentalene skeleton", CrystEngComm 2020, 22, 5949−5953. (DOI: 10.1039/D0CE00878H)

  13. T. Higashino, S. Arai, S. Inoue, S. Tsuzuki, Y. Shimoi, S. Horiuchi, T. Hasegawa, R. Azumi, "Architecting layered molecular packing in substituted benzobisbenzothiophene (BBBT) semiconductor crystals", CrystEngComm 2020, 22, 3618−3626. (DOI: 10.1039/D0CE00285B)

  14. K. Tahara, Y. Ashihara, T. Higashino, Y. Ozawa, T. Kadoya, K. Sugimoto, A. Ueda, H. Mori, M. Abe, "New π-extended catecholato complexes of Pt(II) and Pd(II) containing a benzothienobenzothiophene (BTBT) moiety: synthesis, electrochemical behavior and charge transfer properties", Dalt. Trans. 2019, 48, 7367−7377. (DOI: 10.1039/C8DT05057K)

  15. S. Yokomori, A. Ueda, T. Higashino, R. Kumai, Y. Murakami, H. Mori, "Construction of three-dimensional anionic molecular frameworks based on hydrogen- bonded metal dithiolene complexes and the crystal solvent effect", CrystEngComm 2019, 21, 2940−2948. (DOI: 10.1039/C9CE00364A)

  16. T. Higashino, S. Inoue, Y. Sadamitsu, S. Arai, S. Horiuchi, T. Hasegawa, "Bilayer-type layered herringbone packing in 3-n-octyl-9-phenyl-benzothieno[3,2-b]naphtho[2,3-b]thiophene", Chem. Lett. 2019, 48, 453−456. (DOI: 10.1246/cl.181038)

  17. R. Sato, D. Yoo, T. Higashino, T. Mori, "n-Channel Transistor of 1,5-Dibromo-2,6-naphthoquinhydrone", Chem. Lett. 2019, 48, 264−266. (DOI: 10.1246/cl.181002)

  18. T. Kadoya, R. Oki, Y. Kiyota, Y. Koyama, T. Higashino, K. Kubo, T. Mori, J. Yamada, "Transport Properties of Molecular Conductors (BSBS)2XF6 (X = As, Sb, and Ta): Investigation of Intermolecular Transfer Integrals in the Radical-Cationic State of Benzothienobenzothiophene-Type Semiconductors", J. Phys. Chem. C 2019, 123, 5216−5221. (DOI: 10.1021/acs.jpcc.8b10687)

  19. T. Higashino, A. Ueda, H. Mori, "Di- and Tetramethoxy Benzothienobenzothiophenes: Substitution Position Effects on the Intermolecular Interactions, Crystal Packing and Transistor Properties", New J. Chem. 2019, 43, 884−892. (DOI: 10.1039/C8NJ04251A)

  20. T. Higashino, A. Ueda, J. Yoshida, H. Mori, "Improved Stability of a Metallic State in Benzothienobenzothiophene-Based Molecular Conductors: An Effective Increase of Dimensionality with Hydrogen Bonds", Chem. Commun. 2017, 53, 3426−3429. (DOI: 10.1039/c7cc00784a) Inside Back Cover

  21. K. Iijima, Y. Le Gal, T. Higashino, D. Lorcy, T. Mori, "Birhodanines and Their Sulfur Analogues for Air-Stable n-Channel Organic Transistors", J. Mater. Chem. C 2017, 5, 9121−9127. (DOI: 10.1039/c7tc02886e)

  22. R. Sato, M, Dogishi, T. Higashino, T. Kadoya, T. Kawamoto, T. Mori, "Charge-Transfer Complexes of Benzothienobenzothiophene with Tetracyanoquinodimethane and the n-Channel Organic Field-Effect Transistors", J. Phys. Chem. C 2017, 121, 6561−6568. (DOI: 10.1021/acs.jpcc.7b00902)

  23. T. Higashino, M. Dogishi, T. Kadoya, R. Sato, T. Kawamoto, T. Mori, "Air-Stable n-Channel Organic Field-Effect Transistors Based on Charge-Transfer Complexes Including Dimethoxybenzothienobenzothiophene and Tetracyanoquinodimethane Derivatives", J. Mater. Chem. C ,2016, 4, 5981−5987. (DOI: 10.1039/c6tc01532h)

  24. C. Fujisue, T. Kadoya, T. Higashino, R. Sato, T. Kawamoto, T. Mori, "Air-Stable Ambipolar Organic Transistors Based on Charge-Transfer Complexes Containing Dibenzopyrrolopyrrole", RSC Adv. 2016, 6, 53345−53350. (DOI: 10.1039/c6ra10606d)

  25. M. Ashizawa, N. Masuda, T. Higashino, T. Kadoya, T. Kawamoto, H. Matsumoto, T. Mori, "Ambipolar Organic Transistors Based on Isoindigo Derivatives", Org. Electron. 2016, 35, 95−100. (DOI: 10.1016/j.orgel.2016.05.013)

  26. Y. Kiyota, T. Kadoya, K. Yamamoto, K. Iijima, T. Higashino, T. Kawamoto, K. Takimiya, T. Mori, "Benzothienobenzothiophene-Based Molecular Conductors: High Conductivity, Large Thermoelectric Power Factor, and One-Dimensional Instability", J. Am. Chem. Soc. 2016, 138, 3920−3925. (DOI: 10.1021/jacs.6b01213)

  27. T. Higashino, O. Jeannin, T. Kawamoto, D. Lorcy, T. Mori, M. Fourmigué, "A Single-Component Conductor Based on a Radical Gold Dithiolene Complex with Alkyl-Substituted Thiophene-2,3-dithiolate Ligand", Inorg. Chem. 2015, 54, 9908−9913. (DOI: 10.1021/acs.inorgchem.5b01678)

  28. J. Cho, T. Higashino, T. Mori, "Band-Like Transport Down to 20 K in Organic Single-Crystal Transistors Based on Dioctylbenzothienobenzothiophene", Appl. Phys. Lett. 2015, 106, 193303. (DOI: 10.1063/1.4921343)

  29. A. Filatre-Furcate, T. Higashino, D. Lorcy, T. Mori, "Air-Stable n-Channel Organic Field-Effect Transistors Based on a Sulfur Rich π-Electron Acceptor", J. Mater. Chem. C 2015, 3, 3569−3573. (DOI: 10.1039/c5tc00253b)

  30. T. Higashino, S. Kumeta, S. Tamura, Y. Ando, K. Ohmori, K. Suzuki, T. Mori, "Ambipolar Transistor Properties of 2,2′-Binaphthosemiquinones", J. Mater. Chem. C 2015, 3, 1588−1594. (DOI: 10.1039/c4tc02467b)

  31. T. Higashino, J. Cho, T. Mori, "Extracting Parameters in Ambipolar Organic Transistors Based on Dicyanomethylene Terthiophene", Appl. Phys. Express 2014, 7, 121602. (DOI: 10.7567/APEX.7.121602)

  32. O. Pitayatanakul, T. Higashino, T. Kadoya, M. Tanaka, H. Kojima, M. Ashizawa, T. Kawamoto, H. Matsumoto, K. Ishikawa, T. Mori, "High Performance Ambipolar Organic Field-Effect Transistors Based on Indigo Derivatives", J. Mater. Chem. C 2014, 2, 9311−9317. (DOI: 10.1039/c4tc01563k)

  33. T. Higashino, T. Kadoya, S. Kumeta, K. Kurata, T. Kawamoto, T. Mori, "An Organic Metal Derived from a Selenium Analogue of Benzothienobenzothiophene", Eur. J. Inorg. Chem. 2014, 3895−3898. (DOI: 10.1002/ejic.201402221)

  34. T. Kadoya, M. Ashizawa, T. Higashino, T. Kawamoto, S. Kumeta, H. Matsumoto, T. Mori, "A Highly Conducting Organic Metal Derived from An Organic-Transistor Material: Benzothienobenzothiophene", Phys. Chem. Chem. Phys. 2013, 15, 17818−17822. (DOI: 10.1039/c3cp52881b)

  35. T. Higashino, Y. Akiyama, H. Kojima, T. Kawamoto, T. Mori, "Organic Semiconductors and Conductors with tert-Butyl Substituents", Crystals 2012, 2, 1222−1238. (DOI: 10.3390/cryst2031222)